Once the response to your Availability Request have been received, so you know who is available to play and who isn't, it's time to set up the match event (or multiple matches) and pick the players you want for each squad.
Open the Availability Request
Scroll down to the blue callout and press 'Select people and create event'
When selecting recipients for the event, the members will be divided into sections:
Available
Unanswered
Declined
Other (Players who weren't included in the original availability request
This last options makes it easy to only invite players who have set themselves as available, or include other players if necessary
Once you have selected your recipients, go ahead and set up the event as normal.
It is also possible to message the non-selected members by scrolling down to "Created events" inside the availability request, and then press "message non-selected recipients"
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